Despite the sunny weather, Brigitte, 64, opted for a dark navy dress which featured racy leather panels to the side and under the bust.
She kept her arms covered with a matching zip-front collarless biker jacket.
The French first lady carried a large leather Louis Vuitton handbag on her shoulder in a contrasting blue and red colour.
Smiling broadly, Brigitte had her hair swept up in an elegant French chignon.
Brigitte flashed plenty of jewellery for her visit, all of which could be seen sparkling in the sun.
Two large diamond rings could be seen on each and, and a pretty necklace shimmered just by the collar of her dress.
In keeping with her thick jacket, Brigitte kept her legs covered with American tan tights.
Brigitte kept her make-up simple for the visit, wearing nude lip balm and heavy mascara.
Despite the sunshine, neither Brigitte nor Emmanuel Macron, 39, wore sunglasses.
Brigitte made a more muted appearance today, but yesterday she made sure all eyes were on her as she arrived in Salzburg with her husband.
The former school teacher stepped off the plane wearing a red short sleeve dress which fell above the knee in length.
It featured a zip up front and a zip on the right breast, as well as a biker-jacket-like fastening on the collar.
Brigitte accessorised with a small black satchel and black pointed stiletto heels.
Her hair was perfectly coiffed as usually and a pair of thick black sunglasses finished off the look.
The French President is meeting with the leaders of Austria the Czech Republic and Slovakia as part of a tour of central and eastern Europe aimed at reinvigorating European Union unity after Britain’s decision to leave.
After their arrival the Macrons, the Austrian chancellor, Christian Kern, 52, and his wife, Eveline Steinberger-Kern, 45, took a stroll around the city.