But since the Ole Gunnar Solskjaer’s appointment, Pogba has four goals and three assists for United.
And Mathias, who plays for French side Tours, told French radio station RMC that Mourinho was at fault for the midfielder’s struggles.
“The problem was Mourinho, right down the line,” Pogba’s brother said.
“In the locker room, outside the locker room, everything.
“From what we see of Mourinho, he always wants to be the maestro, the centre of attention.
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“Paul doesn’t even calculate that aspect.
“You respect him, he will respect you, you trust him, he will make you big matches.”
Pogba has arrived in Dubai to link up with his United team-mates on their warm weather training camp.
He missed Saturday’s 2-0 FA Cup win over Reading after being hurt by a tackle from Jonjo Shelvey in United’s 2-0 win over Newcastle last week.
While the majority of the squad flew out to the Middle East on Sunday, World Cup winner remained in Manchester to receive treatment.
But he has been given the all clear to fly out and is in contention to return to the side for this weekend’s clash with Tottenham.
And Phil Jones feels Spurs will be a good test of United’s improvement.
“It is about momentum and we need to keep building that momentum, whoever we play. We are feeling good and we are feeling strong,” he said.
“Spurs is a good test. We are in good form and have some momentum going. We have steadied the ship a bit, if you like, and we need to keep going.
“We have not done anything yet, we have not achieved anything but we need to keep it going.
“Possibly, Spurs will be an indicator for us and how far we can go. It is a game we need to win. They are in good form and doing well and we need to have a good week, train well and prepare for a tough game.
“Hopefully, the momentum can carry us on to win that match
“Of course, we should be in the Champions League next season and that is the aim but we have done nothing yet and I know it is a cliche but it has to be game by game.
“I don’t really want to think about the top four, or the Champions League or the FA Cup, it has to be game by game. Tottenham is tough and we have to see where we are after that.”