Brutal confrontations in the run-up to the match between pro Catalonians and the police saw the game take place behind closed doors.
Police turned on the fans, and the game was played out in front of an empty Nou Camp stadium, a decision which was made by Barca chiefs just 30 minutes before the scheduled kick-off time.
Lionel Messi scored a double, but the result was of secondary importance.
Pique, who is a pro-Catalunya supporter, was left visibly upset by the events.
“There was no act of aggression from the people today and yet the police have acted in the way that they have acted today,” Pique said.
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“It was very difficult to play without our supporters and after all that has happened throughout Catalonia.
“It was my worse experience as a player.
“Grandparents have gone with their grandchildren today and have tried to vote and the images speak for themselves.
“All the protests have been non-violent but everyone has seen the way police reacted today and I think there will be consequences.’
“There were arguments to play the game today just as there were arguments to not play the game.
“In the end the league and Las Palmas wanted to play the game.
“There were all sorts of opinions and in the end the club made the decision to play the game.
“My opinion doesn’t matter very much. Lots of players expressed an opinion before the game.”