Brad and Jennifer met in 1994, but it wasn’t until four years later that they started to date.
In 1999 they made their first official appearance as a couple at The Emmy Awards and two months later they shared news of their engagement.
The next year the couple married in an extravagant ceremony in Malibu, California.
But it wasn’t to last, as four years later Brad started filming Mr and Mrs Smith with Angelina Jolie, who became his second wife.
In January 2005, Hollywood’s ‘Golden Couple’ divorced and Brad went on to marry Angelina, and Jennifer later tied the knot with Justin Theroux.
However both marriages lasted less than five years.
source: express.co.uk