The Red Sox are the clear favourites to win the series, being odds-on with most bookmakers.
Boston have eight World Series titles having most recently lifted the trophy in 2013.
They go into the series having won 108 of their regular season matches while losing 54.
To get into the World Series, they were 3-1 victors over the New York Yankees before a 4-1 win against Houston Astros.
For the Dodgers, they just edged out Colorado Rockies to win the NL West with a 92-71 record.
They then beat Atlanta Braves 3-1 before a 4-3 victory over the Milwaukee Brewers.
The Dodgers have six World Series titles but the last was 30 years ago in 1988.
And here Express Sport runs you through how to see who gets the 2018 title.
How to watch Dodgers vs Red Sox on TV
The MLB World Series is live on BT Sport.
The opening game of the series is live on BT Sport 1 with coverage getting underway at 12.30am.
BT Sport 1 is available on Sky channel 413.
How to watch Dodgers vs Red Sox online
With BT Sports showing the World Series, the match is live for existing customers on their website.
The BT Sport enhanced video player is also available online.
EE mobile customers will be able to stream the game for free, thanks to a free subscription plan recently announced by the network.
“To say thanks for being with us, here’s a special sporting treat for our pay monthly mobile and tablet customers: three months’ free BT Sport on your EE phone and connected tablet,” BT explains.
“Just text SPORT to 150, register for a BT ID then download the BT Sport app and get watching!
“Loads of the UK’s best sporting action, on the UK’s fastest network.”
You can visit the EE website for more information on the BT Sports offer.