Spanish riot police used truncheons and rubber bullets on voters, drawing worldwide criticism and tipping Spain into its biggest constitutional crisis in decades.
Mr Puigdemont’s government is to ask the regional parliament on Monday to declare independence, after his officials released preliminary referendum results showing 90 per cent support in favour of breaking away.
Turnout was only about 43 percent as Catalans who favour remaining part of Spain mainly boycotted the ballot.
Mr Puigdemont said in an interview in the German daily Bild today: “Personally, I am not afraid of that.
“And I’m not surprised anymore about what the Spanish government is doing. My arrest is also possible, which would be a barbaric step.”
Neither the Spanish government nor the judiciary has threatened to arrest Mr Puigdemont, though Madrid accuses him of breaking the law by ignoring a Constitutional Court ruling forbidding the referendum from going ahead.
Mr Puigdemont has said the referendum proved the will of the people was to leave Spain and has vowed to continue with secession, despite Madrid’s insistence it won’t happen.
On Wednesday, in a televised address, Mr Puigdemont renewed his call for international mediation but said the results of the referendum would have to be applied.
The confrontation has raised fears among investors of unrest in Catalonia, which accounts for a fifth of the Spanish economy. A former principality, the region has its own language and culture and has long complained that it pays more to Madrid in taxes than it receives each year from central funding.
The crisis in the eurozone’s fourth-biggest economy has hurt Spanish bond and stock markets. The nation’s borrowing costs hit a seven-month high on Thursday ahead of a government bond auction that will test investor confidence.
Prime Minister Mariano Rajoy has offered to open multi-party talks that could cut a better tax and constitutional deal for Catalonia in return for the region giving up on independence.
But his government has said the region must “return to the path of law” before negotiations can go ahead.
Sunday’s crackdown by Spanish police, Rajoy’s hardline stance and an uncharacteristically strong intervention this week by Spain’s King Felipe VI seems to have deepened Catalonia’s resolve to continue with the project.
“We will go as far as people want it. But without the use of force. We were always a peaceful movement. And I am sure that Spain will not be able to ignore the will of so many people,” Puigdemont told Bild.
Opinion polls conducted before the vote suggested a minority of around 40 per cent of residents in Catalonia backed independence.
But a majority wanted a referendum to be held and the violent police crackdown angered Catalans across the divide.